As an instructor, the Canvas Student View will not load the Library Course Materials page as a student would see it. This is because the Canvas Student View setting does not send the proper student view credentials to the system that displays the Library Course Materials page.

To view the Library Course Materials page as a student, first exit the Canvas Student View.

Open the Library Course Materials page. At the top of the page next to the share icon, click on the three dots "..." and choose View list as a student.